https://powo.science.kew.org/taxon/urn: ... 30000028-2
I may be annoying cactus lovers by calling them areolate purslanes in future
Or local floras:Notes on delimitation
DNA studies show that Portulacaceae possibly cannot be separated from Cactaceae because it lacks autoapomorphies [a distinctive feature, known as a derived trait, that is unique to a given taxon]; Cactaceae however presents areoles which are not present as such in Portulacaceae.
http://www.efloras.org/
It does depend on which country you are going to and how exotic it might be. People are still working on a Flora of Burma/Myanmar and it could be a while before that hits the net. South Africa has an immense amount of its xerophytic flora described online.
If you have a particular genus in mind, somewhere in Africa, the "African Plants a photo guide" can be very helpful. It can't be searched by country but you can specify one-fifth of Africa and the results will tell you in which country they are found.
http://www.africanplants.senckenberg.de ... page_id=81